Nonheme Fe Enzyme‐Catalyzed Enantiodivergent Nitrogen Migration: Directed Evolution and Computational Study of Isopenicillin N Synthases for Biocatalytic Synthesis of Arylglycines

Alkyl Sulfonyl Fluorides as Ambiphiles in the Stereoselective Palladium(II)-Catalysed Cyclopropanation of Unactivated Alkenes

Catalytic Enantioselective Cross-Nucleophile Coupling via Valence Tautomerism

Late-Stage Conversion of Carboxylic Acids to Nitriles with Mg and Pd Cocatalysis

Enantioselective N-Heteroaryl C–H Functionalization for Piperidine-Azine Conjugation: Alkynes as Allylmetal Pronucleophiles in Dearomative Addition-Hydrogen Auto-Transfer

Crystallographic, Electronic Structure, and Computational Studies of PHOX–Ni Aryne Complexes: Origins of Regioselectivity in Metal-Bound Aryne Synthesis and Difunctionalization

De Novo Design, Directed Evolution and Computational Study of Heme-Binding Helical Bundle Protein Catalysts for Biocatalytic Enantioselective Ge–H Insertion

Equivalent Atrop- and Positional Isomerism in Styrene Derivatives Prepared by Enantioselective 1,3-Diarylation

Development of a Ligand for Cu-Catalyzed Amination of Base-Sensitive (Hetero)aryl Chlorides

Fast and Accurate Ring Strain Energy Predictions with Machine Learning and Application in Strain-Promoted Reactions

Cu(II)-Catalyzed Hydrofunctionalization of Unactivated Alkynes via π-Lewis Acid Activation

A Pyridoxal Radical Carboligase and Imine Reductase Photobiocatalytic Cascade for Stereoselective Synthesis of Unnatural Prolines

Diversity-Oriented Method Development: Multifunctional Homoallylic Amines and Azabicyclooctanes Bearing a Bridgehead Enamine

Reactions of Difluorocarbene with Organogold(I) Complexes: Synthesis of gem-Difluoromethylene Organometallics via Difluorocarbene Insertion and Cycloaddition Reactions

Directed Halogen Atom Transfer (DIXAT): A Powerful Tool for Chemoselective Generation of Aryl Radicals Toward Remote C(sp3)–H Functionalization of Aliphatic Amines

Diversity-Oriented Photobiocatalytic Synthesis via Stereoselective Three-Component Radical Coupling

A Database of Steric and Electronic Properties of Heteroaryl Substituents

Copper Hydride-Catalyzed Net Hydroformylation of Unactivated Terminal Olefins

Remote-Markovnikov Hydrobromination and Hydrochlorination of Allyl Carboxylates via Dual Photoredox/Cobalt Catalysis

Nonheme Fe 1,3-Nitrogen Migratases for Asymmetric Noncanonical Amino Acid Synthesis

Enantioconvergent Carbenoid Insertion into Carbon–Boron Bonds

A Class of Benzofuranoindoline-Bearing Heptacyclic Fungal RiPPs with Anticancer Activities

Modular Arene Functionalization by Differential 1,2-Diborylation

Multifunctional Chiral Silanol Ligands for Enantioselective Catalysis

Alkyl Fluoride Synthesis via Cu-Mediated Deacetylative Fluorination

A Predictive Model for Thiol Reactivity of N-Heteroaryl α-Methylene−γ-Lactams—A Medicinally Relevant Covalent Reactive Group

Cooperative Photometallobiocatalysis: Nonheme Fe Enzyme‐Catalyzed Enantioconvergent Radical Decarboxylative Azidation, Thiocyanation, and Isocyanation of Redox‐Active Esters

Modular Silver Catalysts to Elucidate the Role of Non-Covalent Interactions in Asymmetric C‒H Amidation Reactions

De Novo Design of Porphyrin-Containing Proteins as Efficient and Stereoselective Catalysts

Hexafluoroisopropanol Solvent Effects on Enantioselectivity of Dirhodium Tetracarboxylate-Catalyzed Cyclopropanation

Potassium tert-Butoxide Mediated Stereoselective/Direct Mannich Reaction of α-Substituted-γ-Lactams with in situ Generated Aryl N-Silyl Imines

Photoinduced, Copper-Catalyzed Deracemization of Alkyl Halides

Catalytic Enantioselective Smiles Rearrangement Enabled by the Directed Evolution of P450 Radical Aryl Migratases

Excited-State Palladium-Catalyzed Radical Allylic Alkylation: Rapid Access to C2-Allyl Carbohydrates

Aryl Halide Cross-Coupling via Formate-Mediated Transfer Hydrogenation

N-Oxide Insertion into LDA Dimeric Aggregates for Azomethine Ylide Formation: Explicit Solvation in Quantum Mechanical Treatment of Polarized Intermediates

Catalytic Difluorocarbene Insertion Enables Access to Fluorinated Oxetane Isosteres

Mechanistic and Computational Insights into Asymmetric Intramolecular Iron-Catalyzed Nitrene Transfer into Benzylic C–H Bonds

Dual Catalytic C(sp2)–H Activation of Azaheterocycles toward C–N Atropisomers

Iron-Catalyzed Aerobic Carbonylation of Methane via Ligand-to-Metal Charge Transfer Excitation

Dearomative Addition-Hydrogen Autotransfer for Branch-Selective N-Heteroaryl C–H Functionalization via Ruthenium-Catalyzed C–C Couplings of Diene Pronucleophiles

Stereo-Differentiating Asymmetric Rh(I)-Catalyzed Pauson–Khand Reaction: A DFT-Informed Approach to Thapsigargin Stereoisomers

Systematic Parameter Determination Aimed at a Catalyst-Controlled Asymmetric Rh(I)-Catalyzed Pauson–Khand Reaction

Catalytic Prenyl Conjugate Additions for Synthesis of Enantiomerically Enriched PPAPs

Hemilabile and Redox-Active Quinone Ligands Unlock sp3-Rich Couplings in Nickel-Catalyzed Olefin Carbosulfenylation

A Metalloenzyme Platform for Catalytic Asymmetric Radical Dearomatization

Anti-Selective Cyclopropanation of Nonconjugated Alkenes with Diverse Pronucleophiles via Directed Nucleopalladation

On the Gold(I)-Catalyzed Enantioselective Addition of Indole to Diphenylallene via Anion-Binding Catalysis

Ni-Catalysed Dicarbofunctionalization for the Synthesis of Sequence-Encoded Cyclooctene Monomers

Resonance-Assisted Self-Doping in Robust Open-Shell Ladder-Type Oligoaniline Analogues

Synthesis of Z-gem-Cl, CF3-Substituted Alkenes by Stereoselective Cross-Metathesis and the Role of Disubstituted Mo Alkylidenes

Machine Learning-Guided Co-Optimization of Fitness and Diversity Facilitates Combinatorial Library Design in Enzyme Engineering

Copper-Catalyzed Dearomative trans-1,2-Carboamination

Stereospecific Alkenylidene Homologation of Organoboronates by SNV Reaction

Copper-Catalyzed Dearomative 1,2-Hydroamination

CuH-Catalyzed Regio- and Enantioselective Formal Hydroformylation of Vinyl Arenes

Stereoselective Amino Acid Synthesis by Photobiocatalytic Oxidative Coupling

Biocatalytic Enantioselective C(sp3)–H Fluorination Enabled by Directed Evolution of Non-Haem Iron Enzymes

Stereodivergent Photobiocatalytic Radical Cyclization through the Repurposing and Directed Evolution of Fatty Acid Photodecarboxylases

Leveraging the Stereochemical Complexity of Octahedral Diastereomeric-at-Metal Catalysts to Unlock Regio-, Diastereo-, and Enantioselectivity in Alcohol-Mediated C–C Couplings via Hydrogen Transfer

Implementing a Doping Approach for Poly(methyl methacrylate) Recycling in a Circular Economy

A Catalytic Process Enables Efficient and Programmable Access to Precisely Altered Indole Alkaloid Scaffolds

Enantioselective and Regiodivergent Synthesis of Propargyl- and Allenylsilanes through Catalytic Propargylic C−H Deprotonation

Synthesis of Alkenyl Boronates through Stereoselective Vinylene Homologation of Organoboronates

Intramolecular Carboxyamidation of Alkyne‐Tethered O‐Acylhydroxamates through Formation of Fe(III)‐Nitrenoids

Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations of Carbamimidates

Modular Synthesis of 1,2-Azaborines via Ring-Opening BN-Isostere Benzannulation

Palladium/Norbornene-Catalyzed Direct Vicinal Dicarbofunctionalization of Indoles: Reaction Development and Mechanistic Study

ortho-C–H Methoxylation of Aryl Halides Enabled by a Polarity Reversed N–O Reagent

Stereoselective Synthesis of Trisubstituted Alkenes via Copper Hydride-Catalyzed Alkyne Hydroalkylation

Dynamic Kinetic Stereoselective Glycosylation via Rh(II) and Chiral Phosphoric Acid-Cocatalyzed Carbenoid Insertion to Anomeric OH Bond for the Synthesis of Glycoconjugates

Stereoselective Amino Acid Synthesis by Synergistic Photoredox–Pyridoxal Radical Biocatalysis

Enzyme-Controlled Stereoselective Radical Cyclisation to Arenes Enabled by Metalloredox Biocatalysis

Redox-Paired Alkene Difunctionalization Enables Skeletally Divergent Synthesis

Photochemically Driven Nickel-Catalyzed Carboxylative Buchwald Hartwig Amination: Scope and Mechanism

Escape from Palladium: Nickel-Catalyzed Catellani Annulation

Enantioselective Hydroalkenylation and Hydroalkynylation of Alkenes Enabled by a Transient Directing Group: Catalyst Generality through Rigidification

Catalytic Cross-Metathesis Reactions That Afford E- and Z-Trisubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights

Designed Iron Catalysts for Allylic C–H Functionalization of Propylene and Simple Olefins

Synthesis and Characterization of Post-β-Carbon Elimination Organopalladium Complexes

Diastereo- and Enantioselective Synthesis of Compounds with a Trifluoromethyl- and Fluoro-Substituted Carbon Centre

Enantioselective Synthesis of Quaternary Oxindoles: Desymmetrizing Staudinger–Aza-Wittig Reaction Enabled by a Bespoke HypPhos Oxide Catalyst

Catalytic Addition of Nitroalkanes to Unactivated Alkenes via Directed Carbopalladation

Three-Component Asymmetric Ni-Catalyzed 1,2-Dicarbofunctionalization of Unactivated Alkenes via Stereoselective Migratory Insertion

Excited-State Palladium-Catalyzed α-Selective C1-Ketonylation

A Combined DFT, Energy Decomposition, and Data Analysis Approach to Investigate the Relationship Between Noncovalent Interactions and Selectivity in a Flexible DABCOnium/Chiral Anion Catalyst System

Copper Hydride-Catalyzed Enantioselective Olefin Hydromethylation

Mechanistic Basis for the Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates

Thiol Reactivity of N-Aryl α-Methylene-γ-Lactams: Influence of the Guaianolide Structure

Engineered P450 Atom-Transfer Radical Cyclases are Bifunctional Biocatalysts: Reaction Mechanism and Origin of Enantioselectivity

Chiral Amines via Enantioselective π-Allyliridium-C, O-Benzoate-Catalyzed Allylic Alkylation: Student Training via Industrial–Academic Collaboration

Low-Valent Tungsten Redox Catalysis Enables Controlled Isomerization and Cabonylative Functionalization of Alkenes

Synthesis of (+)-Ribostamycin by Catalytic, Enantioselective Hydroamination of Benzene

C–N Bond Forming Radical Rebound Is the Enantioselectivity-Determining Step in P411-Catalyzed Enantioselective C(sp3)–H Amination: A Combined Computational and Experimental Investigation

C2-Ketonylation of Carbohydrates via Excited-State Palladium-Catalyzed 1,2-Spin-Center Shift

Pd(II)-Catalyzed C(alkenyl)–H Activation Facilitated by a Transient Directing Group

Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl−Cu Species

Kinetic, ESI–CID–MS, and Computational Studies of π-Allyliridium C, O-Benzoate-Catalyzed Allylic Amination: Understanding the Effect of Cesium Ion

Excited-State Palladium-Catalyzed Radical Migratory Mizoroki–Heck Reaction Enables C2-Alkenylation of Carbohydrates

Origins of Catalyst-Controlled Selectivity in Ag-Catalyzed Regiodivergent C–H Amination